h-index: 18     i10-index: 25

Photo-Catalysis: A Clear Path to Cleaner Chemistry

Document Type : Review Article

Authors

1 Department of Chemical Science, University of Lakki Marwat, KP, Pakistan

2 Department of Chemistry, Minhaj University, Lahore Punjab, Pakistan

3 Department of Agricultural Chemistry & Biochemistry, University of Agriculture, Peshawar, Khyber Pakhtunkhwa, Pakistan

4 Department of chemical science, University of Lakki Marwat, KP, Pakistan

Abstract
Photocatalysis is a fast-advancing pillar of green chemistry with strong promise for sustainable, energy-efficient environmental remediation. Drawing on studies from 2018–2024, this review surveys progress, challenges, and future directions in semiconductor photocatalysts—emphasizing titanium dioxide (TiO₂) and its modified forms alongside g-C₃N₄ composites and high-entropy oxides—which are valued for low energy demand, operational simplicity, and effective degradation of persistent organic pollutants. Recent design strategies—metal/non-metal doping, heterojunction engineering, and composite construction—have expanded visible-light response, improved light harvesting, and suppressed charge recombination, yielding degradation efficiencies of ~94–96% for model dyes such as methylene blue and methyl orange and delivering ~15–25% gains in quantum efficiency versus conventional systems. Key practical barriers remain, including carrier recombination, photostability over long use, and limits in solar utilization, but converging advances in material architecture and reactor engineering are steadily translating lab performance into scalable, eco-friendly, and cost-effective technologies for industrial wastewater treatment and sustainable chemical manufacturing—pointing to a clear path toward cleaner chemistry.

Graphical Abstract

Photo-Catalysis: A Clear Path to Cleaner Chemistry

Keywords

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[1] Ibhadon, A.O., Fitzpatrick, P., Heterogeneous photocatalysis: Recent advances and applications. Catalysts, 2013, 3(1), 189–218.
[2] Chakravorty, A., Roy, S., A review of photocatalysis, basic principles, processes, and materials. Sustainable Chemistry for the Environment, 2024, 8, 100155.
[3] Mohamadpour, F., Amani, A.M., Photocatalytic systems: Reactions, mechanism, and applications. RSC Advances, 2024, 14(29), 20609–20645.
[4] Hassaan, M.A., El-Nemr, M.A., Elkatory, M.R., Ragab, S., Niculescu, V.-C., El Nemr, A., Principles of photocatalysts and their different applications: A review. Topics in Current Chemistry, 2023, 381(6), 31.
[5] Lobus, N.V., Knyazeva, M.A., Popova, A.F., Kulikovskiy, M.S., Carbon footprint reduction and climate change mitigation: A review of the approaches, technologies, and implementation challenges. C: Journal of Carbon Research, 2023, 9(4), 120.
[6] Chauke, N.M., Mohlala, R.L., Ngqoloda, S., Raphulu, M.C., Harnessing visible light: Enhancing TiO2 photocatalysis with photosensitizers for sustainable and efficient environmental solutions. Frontiers in Chemical Engineering, 2024, 6, 1356021.
[7] Franchi, D., Amara, Z., Applications of sensitized semiconductors as heterogeneous visible-light photocatalysts in organic synthesis. ACS Sustainable Chemistry & Engineering, 2020, 8(41), 15405–15429.
[8] Zarei, M., Wastewater resources management for energy recovery from circular economy perspective. Water-Energy Nexus, 2020, 3, 170–185.
[9] Anucha, C.B., Altin, I., Bacaksiz, E., Stathopoulos, V.N., Titanium dioxide (TiO₂)-based photocatalyst materials activity enhancement for contaminants of emerging concern (CECs) degradation: In the light of modification strategies. Chemical Engineering Journal Advances, 2022, 10, 100262.
[10] Odling, G., Pong, Z.Y., Gilfillan, G., Pulham, C.R., Robertson, N., Bismuth titanate modified and immobilized TiO₂ photocatalysts for water purification: Broad pollutant scope, ease of re-use and mechanistic studies. Environmental Science: Water Research & Technology, 2018, 4(12), 2170–2178.
[11] Dehghani, M.H., Solangi, N.H., Mubarak, N.M., Rajamohan, N., Bosu, S., Othmani, A., Ahmaruzzaman, M., Mishra, S.R., Bhattacharjee, B., Gadore, V., MXene-based materials as adsorbents, photocatalysts, membranes and sensors for detection and removal of emerging and gaseous pollutants: A comprehensive review. Arabian Journal of Chemistry, 2025, 18(1), 106052.
[12] Enesca, A., Isac, L., The influence of light irradiation on the photocatalytic degradation of organic pollutants. Materials, 2020, 13(11), 2494.
[13] Akinnawo, S.O., Ediagbonya, T.F., Advances on modification of photocatalyst for degradation/removal of organic pollutants from water. Cleaner Chemical Engineering, 2025, 100176.
[14] Ghamarpoor, R., Fallah, A., Jamshidi, M., A review of synthesis methods, modifications, and mechanisms of ZnO/TiO2-based photocatalysts for photodegradation of contaminants. ACS Omega, 2024, 9(24), 25457–25492.
[15] Imtiaz, F., Rashid, J., Xu, M., Semiconductor nanocomposites for visible light photocatalysis of water pollutants. Concepts of semiconductor photocatalysis, IntechOpen, 2019.
[16] Fatima, R., Kadhem, A.A., Sajjad, A., Noman, H.M., Kiran, K., Kumar, S., Sunitha, S., Ray, S., Sariyevich, X.X., Fozil, X., Optimized Cu/Zr Co-doped TiO2 nanocomposites as high performance photocatalyst for visible light induced methylene blue degradation. Journal of Alloys and Compounds, 2025, 184031.
[17] Liang, X., Yu, S., Meng, B., Wang, X., Yang, C., Shi, C., Ding, J., Advanced TiO2-based photoelectrocatalysis: Material modifications, charge dynamics, and environmental–energy applications. Catalysts, 2025, 15(6), 542.
[18] Pavel, M., Anastasescu, C., State, R.-N., Vasile, A., Papa, F., Balint, I., Photocatalytic degradation of organic and inorganic pollutants to harmless end products: Assessment of practical application potential for water and air cleaning. Catalysts, 2023, 13(2), 380.
[19] Rad, F.A., Mehrabad, J.T., Esrafili, M.D., A communal experimental and DFT study on structural and photocatalytic properties of nitrogen-doped TiO2. Advanced Journal of Chemistry, Section A, 2023, 6(3), 244–252.
[20] Takanabe, K., Photocatalytic water splitting: Quantitative approaches toward photocatalyst by design. Acs Catalysis, 2017, 7(11), 8006–8022.
[21] Zhou, H., Wang, H., Yue, C., He, L., Li, H., Zhang, H., Yang, S., Ma, T., Photocatalytic degradation by TiO2-conjugated/coordination polymer heterojunction: Preparation, mechanisms, and prospects. Applied Catalysis B: Environment and Energy, 2024, 344, 123605.
[22] Lakhera, S.K., Kangeyan, K.P., Yazhini S, C., Golda A, S., Bernaurdshaw, N., Advances in hybrid strategies for enhanced photocatalytic water splitting: Bridging conventional and emerging methods. Applied Physics Reviews, 2024, 11(4).
[23] Deng, L., Wang, S., Liu, D., Zhu, B., Huang, W., Wu, S., Zhang, S., Synthesis, characterization of fe-doped TiO2 nanotubes with high photocatalytic activity. Catalysis Letters, 2009, 129(3), 513–518.
[24] De Jager, T., Cockrell, A., Du Plessis, S., Ultraviolet light induced generation of reactive oxygen species. Ultraviolet Light in Human Health, Diseases and Environment, 2017, 15–23.
[25] Pourmadadi, M., Holghoomi, R., Maleki-baladi, R., Rahdar, A., Pandey, S., Copper nanoparticles from chemical, physical, and green synthesis to medicinal application: A review. Plant Nano Biology, 2024, 8, 100070.
[26] Meng, S., Zhang, J., Chen, S., Zhang, S., Huang, W., Perspective on construction of heterojunction photocatalysts and the complete utilization of photogenerated charge carriers. Applied Surface Science, 2019, 476, 982–992.
[27] Ahmadlouydarab, M., Javadi, S., Darab, F.A.A., Evaluation of thermal stability of TiO2 applied on the surface of a ceramic tile to eliminate methylene blue using silica-based doping materials. Advanced Journal of Chemistry, Section A, 2023, 6(4), 352–365.
[28] Pipil, H., Yadav, S., Chawla, H., Taneja, S., Verma, M., Singla, N., Haritash, A., Comparison of TiO2 catalysis and fenton’s treatment for rapid degradation of remazol red dye in textile industry effluent. Rendiconti Lincei. Scienze Fisiche e Naturali, 2022, 33(1), 105–114.
[29] Khairutdinov, R.F., Chemistry of semiconductor nanoparticles. Russian Chemical Reviews, 1998, 67(2), 109–122.
[30] Chatenet, M., Pollet, B.G., Dekel, D.R., Dionigi, F., Deseure, J., Millet, P., Braatz, R.D., Bazant, M.Z., Eikerling, M., Staffell, I., Water electrolysis: From textbook knowledge to the latest scientific strategies and industrial developments. Chemical Society Reviews, 2022, 51(11), 4583–4762.
[31] Prakruthi, K., Ujwal, M.P., Yashas, S.R., Mahesh, B., Kumara Swamy, N., Shivaraju, H.P., Recent advances in photocatalytic remediation of emerging organic pollutants using semiconducting metal oxides: An overview. Environmental Science and Pollution Research, 2022, 29(4), 4930–4957.
[32] Schieber, M., Chandel, N.S., ROS function in redox signaling and oxidative stress. Current biology, 2014, 24(10), R453–R462.
[33] Liu, Y., Yuan, Y., Wang, Y., Ngo, H.H., Wang, J., Research and application of active species based on high-valent iron for the degradation of pollutants: A critical review. Science of the Total Environment, 2024, 924, 171430.
[34] Vedhanarayanan, B., Lakshmi, K.S., Lin, T.-W., Interfacial tuning of polymeric composite materials for high-performance energy devices. Batteries, 2023, 9(10), 487.
[35] Akinyemi, A., Agboola, O., Alagbe, E., Igbokwe, E., The role of catalyst in the adsorption of dye: Homogeneous catalyst, heterogeneous catalyst, and advanced catalytic activated carbon, critical review. Desalination and Water Treatment, 2024, 320, 100780.
[37] Hou, H., Shao, G., Yang, W., Recent advances in g-C3N4-based photocatalysts incorporated by Mxenes and their derivatives. Journal of Materials Chemistry A, 2021, 9(24), 13722–13745.
[38] Tsubota, H., Jitianu, A., Kawamura, G., Recent advances in high-entropy oxides for photocatalytic applications. ACS Materials Letters, 2025, 7(3), 1042–1056.
[40] Nawaz, M.N., Zhang, Z., Yuan, W., Khan, S.B., Photocatalytic enhancement of TiO2 through silver, gold, and platinum doping. Energy Nexus, 2025, 100495.
[41] Amani, A.M., Abbasi, M., Najdian, A., Mohamadpour, F., Kasaee, S.R., Kamyab, H., Chelliapan, S., Shafiee, M., Tayebi, L., Vaez, A., MXene-based materials for enhanced water quality: Advances in remediation strategies. Ecotoxicology and Environmental Safety, 2025, 291, 117817.
[42] Hou, H., Shao, G., Yang, W., Recent advances in in g-C₃N₄-based photocatalysts incorporated by MXenes and their derivatives. Journal of Materials Chemistry A, 2021, 9(24), 13722–13745.
[44] Belver, C., Bedia, J., Gómez-Avilés, A., Peñas-Garzón, M., Rodriguez, J.J., Semiconductor photocatalysis for water purification, Nanoscale Materials in Water Purification, 2019, 581–651.
[45] Goodarzi, N., Ashrafi-Peyman, Z., Khani, E., Moshfegh, A.Z., Recent progress on semiconductor heterogeneous photocatalysts in clean energy production and environmental remediation. Catalysts, 2023, 13(7), 1102.
[46] Iyyappan, J., Gaddala, B., Gnanasekaran, R., Gopinath, M., Yuvaraj, D., Kumar, V., Critical review on wastewater treatment using photo catalytic advanced oxidation process: Role of photocatalytic materials, reactor design and kinetics. Case Studies in Chemical and Environmental Engineering, 2024, 9, 100599.
[47] Ekins, P., Zenghelis, D., The costs and benefits of environmental sustainability. Sustainability Science, 2021, 16(3), 949–965.
[48] Constantino, D.S., Dias, M.M., Silva, A.M., Faria, J.L., Silva, C.G., Intensification strategies for improving the performance of photocatalytic processes: A review. Journal of Cleaner Production, 2022, 340, 130800.
[49] Gowland, D.C., Robertson, N., Chatzisymeon, E., Life cycle assessment of immobilised and slurry photocatalytic systems for removal of natural organic matter in water. Environments, 2024, 11(6), 114.
[50] Arjomandi Rad, F., Talat Mehrabad, J., Exploring the photocatalytic activity of magnesium and copper-doped titanium dioxide nano catalyst through synthesis and characterization. Advanced Journal of Chemistry, Section A, 2024, 7, 374–385.
[51] Roberts, K., Dowell, A., Nie, J.-B., Attempting rigour and replicability in thematic analysis of qualitative research data; a case study of codebook development. BMC Medical Research Methodology, 2019, 19(1), 1–8.
[52] do Nascimento, J.L.A., Chantelle, L., dos Santos, I.M.G., Menezes de Oliveira, A.L., Alves, M.C.F., The influence of synthesis methods and experimental conditions on the photocatalytic properties of SnO2: A review. Catalysts, 2022, 12(4), 428.
[54] Hassan, M.K., Karim, M.T., Biswas, P., Howlader, D., Harun-Ur-Rashid, M., Kumer, A., Computational investigation for tetragonal crystals of Zn(GaS2)2, Zn(GaSe2)2, and Zn(GaTe2)2 photocatalysts for wastewater treatment: First principle approaches. Advanced Journal of Chemistry, Section B: Natural Products and Medical Chemistry, 2024, 6(1), 46-66.
[55] van Brederode, M.E., Zoon, S.A., Meeter, M., Examining the effect of lab instructions on students' critical thinking during a chemical inquiry practical. Chemistry Education Research and Practice, 2020, 21(4), 1173–1182.
[56] Sahu, S.K., Palai, A., Sahu, D., Photocatalytic applications of metal oxide-based nanocomposites for sustainable environmental remediation. Sustainable Chemistry for the Environment, 2024, 8, 100162.
[57] Anaya-Rodríguez, F., Durán-Álvarez, J.C., Drisya, K., Zanella, R., The challenges of integrating the principles of green chemistry and green engineering to heterogeneous photocatalysis to treat water and produce green H2. Catalysts, 2023, 13(1), 154.
[58] Huang, R., Zhao, H., Chen, Z., High-entropy materials for photocatalysis. Nano Materials Science, 2024,
[60] Li, Y., Zhou, M., Cheng, B., Shao, Y., Recent advances in g-C3N4-based heterojunction photocatalysts. Journal of Materials Science & Technology, 2020, 56, 1–17.
[61] Ajmal, Z., Tu, X., Abbas, W., Ibrahim, E.H., Ali, H., Hussain, I., Al-Muhana, M.K., Khered, M., Iqbal, A., Rahaman, S., Recent advances in carbon-nitride based advance materials: Synthesis, characterization and photo-electrochemical energy application: Key challenges and prospects. Fuel, 2024, 378, 132903.
[62] Che, L., Pan, J., Cai, K., Cong, Y., Lv, S.-W., The construction of p-n heterojunction for enhancing photocatalytic performance in environmental application: A review. Separation and Purification Technology, 2023, 315, 123708.
[63] Li, Y., Wang, H., Wang, S., Xu, J., Lee, Y.H., Dev, S., BSANet: A bilateral segregation and aggregation network for real-time cloud segmentation. Remote Sensing Applications: Society and Environment, 2025, 38, 101536.
[64] Silva, G.A., Introduction to nanotechnology and its applications to medicine. Surgical Neurology, 2004, 61(3), 216–220.
Volume 7, Issue 2
Spring 2026
Pages 89-112

  • Receive Date 09 August 2025
  • Revise Date 03 November 2025
  • Accept Date 12 November 2025