h-index: 18     i10-index: 25

Comparative Analysis of Pyrolysis of Polystyrene and ‎Low-Density Polyethylene for Sustainable Energy and ‎Plastic Waste Management under Laboratory ‎Conditions

Document Type : Original Research Article

Authors

Department of Polymer and Textile Engineering, Federal University of Technology, Nigeria

Abstract
Nigeria’s 2.5-million-ton plastic waste crisis demands sustainable solutions. This study compared thermal pyrolysis of polystyrene (PS), low-density polyethylene (LDPE), and a 50:50 LDPE-PS mixture chosen arbitrarily, in a fixed-bed batch reactor at 450 °C under nitrogen. Yields were measured by mass, and oils were analyzed for density, viscosity, and composition. PS yielded 97.0 ± 1.2 wt% liquid fuel, 2.5 ± 0.3 wt% gas, and 0.5 ± 0.1 wt% char (Table 1), outperforming LDPE (74.7 ± 1.5 wt% liquid) and the mixture (88.0 ± 1.3 wt% liquid). PS oil’s low density (0.886 g/cm³) and high carbon content (92.1 wt%, Table 3) suit fuel applications, while LDPE’s profile (87.8 wt\% carbon) aligns with diesel (Table 2). The mixture provides versatility for mixed-waste processing. Pyrolysis reduces reliance on landfills, generates revenue, and supports Nigeria’s energy security.

Graphical Abstract

Comparative Analysis of Pyrolysis of Polystyrene and ‎Low-Density Polyethylene for Sustainable Energy and ‎Plastic Waste Management under Laboratory ‎Conditions

Keywords

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Volume 6, Issue 3
Spring 2025
Pages 275-281

  • Receive Date 06 April 2025
  • Revise Date 15 May 2025
  • Accept Date 07 June 2025