h-index: 18     i10-index: 25

Performance and Emission Characteristics of a Spark Ignition Engine Fueled With Gasoline–Bioethanol Blends Derived from Different Biomass Sources

Document Type : Review Article

Authors

1 Mechanical Engineering, Faculty of Engineering and Engineering Technology, atbu Bauchi, Nigeria

2 Department of Automotive Engineering, Faculty of Engineering and Engineering Technology, Atbu Bauchi, Nigeria

3 Department of Mechanical Engineering, Faculty of Engineering and Engineering technology, Atbu Bauchi, Nigeria

4 Department of Mechanical/Production Engineering, Faculty of Engineering and Engineering Technology, Abubakar Tafawa Balewa Univer-sity, Bauchi, Nigeria

Abstract
The growing need for cleaner energy sources has positioned bioethanol as a viable alternative to gasoline in spark-ignition engines. This overview examines how blending gasoline with bioethanol from diverse feedstocks like sugarcane, corn, lignocellulosic materials, and algae impacts engine performance and emissions. Bioethanol's high oxygen content and octane rating enhance combustion, reducing carbon monoxide and hydrocarbon emissions. However, its lower energy density may compromise power output and efficiency. The effect on nitrogen oxides (NOₓ) is condition-dependent: while certain blends (E10–E20) may lower NOₓ due to cooler combustion, higher blends or specific load conditions can increase NOₓ formation. Blends containing 10–30% ethanol typically improve thermal efficiency and reduce emissions without requiring significant engine modifications. Higher ethanol blends might increase fuel consumption and cold-start difficulties. While second-generation bioethanol offers substantial environmental advantages, its production poses challenges. This review identifies the key research gap: the need to optimize higher ethanol blends and clarify NOₓ behavior under different operating conditions. Blends with up to 30% ethanol strike a balance between performance and sustainability, making them a practical choice.

Graphical Abstract

Performance and Emission Characteristics of a Spark Ignition Engine Fueled With Gasoline–Bioethanol Blends Derived from Different Biomass Sources

Keywords

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[1] Algheryani, K.M., El-Behlil, M.A., Alsghayer, M.A. Investigating the environmental impact of NOₓ and CO₂ emissions levels from Al-Khums electric power generation plant on surrounding urban areas using air dispersion model. Journal of Engineering in Industrial Research, 2024, 5(2), 65–80.
[2] Agarwal, A.K., Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines. Progress in Energy and Combustion Science, 2007, 33(3), 233–271.
[3] Al-Hasan, M., Effect of ethanol–unleaded gasoline blends on engine performance and exhaust emission. Energy Conversion and Management, 2003, 44(9), 1547–1561.
[4] Allmägi, R., Jansons, M., Ritslaid, K., Ilves, R., Ethanol utilization in spark-ignition engines and emission characteristics. Bioethanol: A Green Energy Substitute for Fossil Fuels, 2023, 255–277.
[5] Anderson, J., DiCicco, D., Ginder, J., Kramer, U., Leone, T., Raney-Pablo, H., Wallington, T., High octane number ethanol–gasoline blends: Quantifying the potential benefits in the united states. Fuel, 2012, 97, 585–594.
[6] Balat, M., Balat, H., Öz, C., Progress in bioethanol processing. Progress in Energy and Combustion Science, 2008, 34(5), 551–573.
[8] Yousefi, R., Mokaramiyan, S. Study on the production of greenhouse gases in the industrial and power plant sectors of Iran from 1996 to 2017. Journal of Engineering in Industrial Research, 2025, 6(3), 223–243.
[9] Chisti, Y., Biodiesel from microalgae. Biotechnology Advances, 2007, 25(3), 294–306.
[10] Costa, R.C., Sodré, J.R., Hydrous ethanol vs. Gasoline-ethanol blend: Engine performance and emissions. Fuel, 2010, 89(2), 287–293.
[11] Demirbas, A., Progress and recent trends in biofuels. Progress in Energy and Combustion Science, 2007, 33(1), 1–18.
[13] Doğan, B., Erol, D., Yaman, H., Kodanli, E., The effect of ethanol-gasoline blends on performance and exhaust emissions of a spark ignition engine through exergy analysis. Applied Thermal Engineering, 2017, 120, 433–443.
[14] Elfasakhany, A., Investigations on the effects of ethanol–methanol–gasoline blends in a spark-ignition engine: Performance and emissions analysis. Engineering Science and Technology, an International Journal, 2015, 18(4), 713–719.
[15] Gnansounou, E., Dauriat, A., Techno-economic analysis of lignocellulosic ethanol: A review. Bioresource Technology, 2010, 101(13), 4980–4991.
[16] Goldemberg, J., The brazilian biofuels industry. Biotechnology for Biofuels, 2008, 1(1), 6.
[17] Hansen, A.C., Zhang, Q., Lyne, P.W., Ethanol–diesel fuel blends––a review. Bioresource Technology, 2005, 96(3), 277–285.
[18] Hsieh, W.-D., Chen, R.-H., Wu, T.-L., Lin, T.-H., Engine performance and pollutant emission of an SI engine using ethanol–gasoline blended fuels. Atmospheric Environment, 2002, 36(3), 403–410.
[19] Iodice, P., Langella, G., Amoresano, A., Ethanol in gasoline fuel blends: Effect on fuel consumption and engine out emissions of si engines in cold operating conditions. Applied Thermal Engineering, 2018, 130, 1081–1089.
[21] Kalam, M., Masjuki, H., Emissions and deposit characteristics of a small diesel engine when operated on preheated crude palm oil. Biomass and Bioenergy, 2004, 27(3), 289–297.
[22] Kalvakala, K.C., Singh, H., Pal, P., Gonzalez, J.P., Kolodziej, C.P., Aggarwal, S.K., Computational study on the impact of gasoline-ethanol blending on autoignition and Soot/NOx emissions under gasoline compression ignition conditions, 2024.
[23] Abedin, M.J., Imran, A., Masjuki, H.H., Kalam, M.A., Shahir, S.A., Varman, M., Ruhul, A.M. An overview on comparative engine performance and emission characteristics of different techniques involved in diesel engine as dual‑fuel engine operation. Renewable and Sustainable Energy Reviews, 2016, 60, 306–316.
[24] Phuangwongtrakul, S., Wechsatol, W., Sethaput, T., Suktang, K., Wongwises, S. Experimental study on sparking ignition engine performance for optimal mixing ratio of ethanol–gasoline blended fuels. Applied Thermal Engineering, 2016, 100, 869–879.
[25] Koç, M., Sekmen, Y., Topgül, T., Yücesu, H.S., The effects of ethanol–unleaded gasoline blends on engine performance and exhaust emissions in a spark-ignition engine. Renewable Energy, 2009, 34(10), 2101–2106.
[26] Kumar, P., Barrett, D.M., Delwiche, M.J., Stroeve, P., Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Industrial & Engineering Chemistry Research, 2009, 48(8), 3713–3729.
[30] Kunwer, R., Pasupuleti, S.R., Bhurat, S.S., Gugulothu, S.K., Rathore, N., Blending of ethanol with gasoline and diesel fuel–a review. Materials Today: Proceedings, 2022, 69, 560–563.
[31] Leach, F., Kalghatgi, G., Stone, R., Miles, P., The scope for improving the efficiency and environmental impact of internal combustion engines. Transportation Engineering, 2020, 1, 100005.
[32] Lee, S.,. Lim, D.K., Beak, S.Y., Seo, D., Park, J.S., Kwak, B.M., Won, J., Lee, J., Kim, B., Quantitative analyses of essential fatty acids in cereals and green vegetables by isotope dilution-gas chromatography/mass spectrometry. Journal of Analytical Science and Technology, 2020, 11, (37), 1-8.
[33] Solmaz, H. Combustion, performance and emission characteristics of fusel oil in a spark ignition engine. Fuel Processing Technology, 2015, 133, 20–28.
[34] Lapuerta, M., Armas, O., Rodriguez-Fernandez, J., Effect of biodiesel fuels on diesel engine emissions. Progress in energy and combustion science, 2008, 34(2), 198–223.
[35] Mahmoud, A., Kwada, S., Jauro, A., Abubakar, A., Production and biodegradability of biodiesel from lagenaria siceraria seed oil. International Journal of Research and Innovation in Applied Science, 2020, 5(3), 94–98.
[36] Mendiburu, A.Z., Lauermann, C.H., Hayashi, T.C., Mariños, D.J., da Costa, R.B.R., Coronado, C.J., Roberts, J.J., de Carvalho Jr, J.A., Ethanol as a renewable biofuel: Combustion characteristics and application in engines. Energy, 2022, 257, 124688.
[37] Mirhashemi, F.S., Sadrnia, H., NOX emissions of compression ignition engines fueled with various biodiesel blends: A review. Journal of the Energy Institute, 2020, 93(1), 129–151.
[39] Mohammed, M.K., Balla, H.H., Al-Dulaimi, Z.M.H., Kareem, Z.S., Al-Zuhairy, M.S., Effect of ethanol-gasoline blends on si engine performance and emissions. Case Studies in Thermal Engineering, 2021, 25, 100891.
[40] Mueller, S., Dennison, G., Liu, S., An assessment on ethanol-blended gasoline/diesel fuels on cancer risk and mortality. International Journal of Environmental Research and Public Health, 2021, 18(13), 6930.
[41] Markou, G., Nerantzis, E., Microalgae for high-value compounds and biofuels production: A review with focus on cultivation under stress conditions. Biotechnology Advances, 2013, 31(8), 1532–1542.
[42] Meena, P.K., Pal, A., Gautam, S., Investigation of combustion and emission characteristics of an SI engine operated with compressed biomethane gas, and alcohols. Environmental Science and Pollution Research, 2024, 31(7), 10262–10272.
[43] Khanna, S., Dewangan, A.K., Yadav, A.K., Ahmad, A. A progressive review on strategies to reduce exhaust emissions from diesel engine: current trends and future options. Environmental Progress & Sustainable Energy, 2025, 44(5).
[44] Nunta, R., Techapun, C., Sommanee, S., Mahakuntha, C., Porninta, K., Punyodom, W., Phimolsiripol, Y., Rachtanapun, P., Wang, W., Zhuang, X., Valorization of rice straw, sugarcane bagasse and sweet sorghum bagasse for the production of bioethanol and phenylacetylcarbinol. Scientific Reports, 2023, 13(1), 727.
[45] Qin, A., Lam, J.W.Y., Tang, B.Z. Luminogenic polymers with aggregation‑induced emission characteristics. Progress in Polymer Science, 2012, 37(1), 182–209.
[46] Naik, S.N., Goud, V.V., Rout, P.K., Dalai, A.K., Production of first and second generation biofuels: A comprehensive review. Renewable and Sustainable Energy Reviews, 2010, 14(2), 578–597.
[47] Olawore, A., Oseni, W., Oladosu, K., Fadele, E., Performance evaluation of a single cylinder spark ignition engine fuelled by mixing ethanol and gasoline. Journal of Applied Sciences and Environmental Management, 2021, 25(6), 971–976.
[48] Örs, İ., Yelbey, S., Gülcan, H.E., Kul, B.S., Ciniviz, M., Evaluation of detailed combustion, energy and exergy analysis on ethanol-gasoline and methanol-gasoline blends of a spark ignition engine. Fuel, 2023, 354, 129340.
[49] Ekpan, F.D.M., Ori, M.O., Samuel, H.S., Egwuatu, O.P. Emerging technologies for eco‑friendly production of bioethanol from lignocellulosic waste materials. Eurasian Journal of Science and Technology, 2024, 4(3), 179–194.
[50] Rao, R.N., Silitonga, A.S., Shamsuddin, A.H., Milano, J., Riayatsyah, T.M.I., Sebayang, A., Nur, T.B., Sabri, M., Yulita, M., Sembiring, R., Effect of ethanol and gasoline blending on the performance of a stationary small single cylinder engine. Arabian Journal for Science and Engineering, 2020, 45(7), 5793–5802.
[51] Rezania, S., Oryani, B., Cho, J., Talaiekhozani, A., Sabbagh, F., Hashemi, B., Rupani, P.F., Mohammadi, A.A., Different pretreatment technologies of lignocellulosic biomass for bioethanol production: An overview. Energy, 2020, 199, 117457.
[52] Ori, M.O., Ime, E.P., Ekpan, F.D.M., Samuel, H.S., Egwuatu, O.P., Ajor, E.J. Revisiting on applications of industrial filters in enhancing polymer product quality and performance. Eurasian Journal of Science and Technology, 2024, 4(2), 116–132.
[53] Dec, J.E., Sjöberg, M., Hwang, W. Isolating the effects of EGR on HCCI heat‑release rates and NOₓ emissions. SAE International Journal of Engines, 2010, 2(2), 58–70.
[54] Abdu Yusuf, A., L Inambao, F., Bioethanol production techniques from lignocellulosic biomass as alternative fuel: A review. International Journal of Mechanical Engineering and Technology, 2019, 10(6), 34–71.
[56] Zakaria, Z., Kheiralla, A., Tola, E., Al-Gaadi, K.A., Alameen, A.A., Zeyada, A.M., Hydrous ethanol-gasoline blends as alternative fuels for spark ignition engine: Fuel properties and engine performance, International Energy Journal, 2022, 22(3), 245–254.
[57] Dijkman, T.J., Benders, R.M.J. Comparison of renewable fuels based on their land use using energy densities. Renewable and Sustainable Energy Reviews, 2010, 14(9), 3148–3155.          
[58] Santos et al. (2021). Effect of ethanol–gasoline blends on SI engine performance and emissions. Case Studies in Thermal Engineering, 25, 100891.
Volume 7, Issue 2
Spring 2026
Pages 139-148

  • Receive Date 22 July 2025
  • Revise Date 22 October 2025
  • Accept Date 16 November 2025